Group for Applied Materials and Electrochemistry
Specific mission
The Group for Applied Materials and Electrochemistry (GAME Lab) is part of the Chemistry, Energy and Technology (CHENERGY) division within the Department of Applied Science and Technology (DISAT) of the Polytechnic of Torino. The GAME Lab research activity is mainly focused on analysing all the aspects related to innovative electrochemical systems for energy storage, which are fundamental to fully exploiting the potential of new technologies, such as smart electronics, energy generation from renewable sources and electric transport. The interests and skills of the GAME Lab concern the development of new materials (nanostructured electrodes and advanced polymeric/composite electrolytes) and innovative technologies for highly performant, safe, lightweight, low-cost, sustainable and environmental-friendly devices, such as lithium and sodium batteries, new zinc-ion and zinc-air batteries, lithium-sulfur batteries and supercapacitors, as well as new generations of photovoltaic and photoelectrochromic devices and materials for the reversible capture and storage of CO2.
Main research topics
- Development and characterisation of innovative polymer electrolytes, including single ion conductors and self-healing materials, with high ionic conductivity and electrochemical stability, safe and with high mechanical properties, to be used in electrochemical energy generators and accumulators.
- Development and characterisation of innovative ceramic electrolytes and polymer/ceramic composites with high ionic conductivity and electrochemical stability, safe and highly performant in lithium-ion batteries, lithium metal batteries and post-lithium devices.
- Development of aqueous, and/or polymeric, and/or organic-inorganic hybrid electrolytes (e.g., based on either ionic liquids or on deep eutectic solvents) for new generation energy storage and conversion devices: supercapacitors, zinc-air cells, water-based solar cells, photoelectrochromic smart windows.
- Use of innovative and/or bioderived materials, such as natural fibers or recycled polymers, as binders in electrodes and/or as electrolyte separators to develop eco-friendly and sustainable energy storage and conversion devices.
- Synthesis and characterisation of nanostructured materials (oxides, phosphates, carbonaceous materials derived from the pyrolysis of food, agricultural and industrial wastes, graphene and new generation 2D-materials) for high energy and/or power density lithium-ion batteries and post-lithium energy storage systems, e.g. based on sodium, zinc and lithium-sulphur.
- Use of advanced electrochemical techniques and computational modelling for the synthesis of new materials, for graphite expansion, for the transformation of natural fibers, and for reversible CO2 capture and storage.
- Assembly of energy storage and conversion devices in controlled atmosphere environment such, as dry-room or glove-box, at lab and/or pre-industrial scale, and their electrochemical characterisation through cyclic voltammetry, galvanostatic cycling and impedance spectroscopy.
Main partnerships
Within the Polytechnic of Torino, the GAME Lab mostly collaborates with the following research groups:
- GLANCE (Glasses Ceramics and Composites) - DISAT
- LaTEST (Laboratory for Theoretical and Experimental Superconducting Tunnelling) - DISAT
- SIMTI (Materials Science and Engineering for Innovative Technologies) – DISAT
- MPMNT (Materials and Processes for Micro & Nano Technologies Team) – DISAT
- MOG (Microwaves and Optoelectronics Group) - DET
- SMALL (multi-Scale ModeLing Laboratory) – DENERG
- Active member of the interdepartmental research laboratory GRAPHENE @ PoliTO
- Active member of the interdepartmental research laboratory ENERGY CENTER @ PoliTO
- Active member of the research hub BIOCHAR @Polito
The GAME Lab has many collaborations with important Italian universities, consortia and research centers. Hereafter, the most significant collaborations are listed:
- Proff. C. Barolo, G. Viscardi e S. Bordiga - University of Torino
- Prof. L. Marchese - University of Eastern Piedmont “Amedeo Avogadro”
- Proff. B. Bozzini - Politecnico di Milano
- Prof. M. Pavone and A.B. Munoz Garcia - University of Naples“Federico II”
- Prof. R. Ruffo and P. Mustarelli - University of Milano Bicocca
- Prof. E. Quartarone - University of Pavia
- Proff. S. Brutti and M.A. Navarra - University of Roma “La Sapienza”
- Prof. F. Nobili - University of Camerino
- Prof. S. Licoccia - University of Roma “Tor Vergata”
- Prof. V. Di Noto - University of Padova
- Dr. P.P. Prosini and M. Moreno - ENEA Casaccia
- Dr. S. Marchionna and I. Quinzeni - RSE
- Dr. A. Di Blasi and V. Antonucci – CNR ITAE
- Dr. A. Paolone – CNR ISC
- Dr. M. Giuliano and V. Ravello – CRF
- Prof. A. Caneschi and Prof. F. Bondioli – INSTM Consortium
- Co-founder and active member of the GISEL (Italian group for electrochemical energy storage) network and the National Centre of Reference for Electrochemical Energy Storage Systems (GISEL-INSTM)
The GAME Lab is actively involved in many collaborations and research projects with international research centers, both European and extra-European, e.g.:
- Dr. R. Salòt and Dr. S. Franger - CEA-Leti e CEA-Liten, Commisariat Energie Atomique, Grenoble FR
- Dr. D. Beneventi and Dr. D. Chaussy - INPG, Grenoble Institute of Technology, Grenoble FR
- Prof. A. Tuel - Institut de recherches sur la catalyse et l'environnement, IRCELYON, Lyon, FR
- Prof. D. Mecerreyes - Institute for Polymer Materials of the University of the Basque Country, POLYMAT, SP
- Prof. J. Maier and Dr. J. Popovic - Max Planck Institute for Solid State Research, Munchen, DE
- Prof. M. Grätzel and Prof. A. Hagfeldt - EPFL - École polytechnique fédérale de Lausanne, SUI
- Prof. D. Brandell and Prof. K. Edstrom - University of Uppsala, SVE
- Prof. A. Cornell - KTH Royal Institute of Technology, Svezia
- Prof. S. Passerini - Helmholtz Institute Ulm - Battery Research Center, KIT, DE
- Prof. J.L. Tirado - University of Córdoba, ES
- Dr. P.P. Pescarmona - University of Groningen, NE
- Dr. A.S. Shaplov – LIST, Luxembourg
- Dr. G. Leftheriotis - University of Patras, GR
- Dr. M. Hayes and Dr. G. Fagas - Tyndall National Institute, National University of Ireland, IR
- Prof. F. Kleitz - University of Wien, Austria
- Dr. A.M. Stephan - Central Electrochemical Research Institute, CECRI, India
- Prof. M. Dinca - MIT- Massachusetts Institute of Technology, USA
- Dr. Iratxe De Meatza - CIDETEC, ES
- Prof. A. Arques Sanz - Universidad Politécnica de Valencia, ES
- Prof. A. Ahmad and Dr. M.S. Su’ait - Universiti Kebangsaan Malaysia, MY
- Prof. A. Balducci – University of Jena, GER
- Dr. Jijeesh R. Nair - Fraunhofer IWKS, GER
- Prof. Joan J. Manyà – University of Zaragoza, SP
- Blue Solutions
- CATL
- COMAU
- DIRECTA PLUS
- ENI
- FAAM (SERI Group SpA, http://www.serispa.it/)
- INSTM
- ITALGAS
- IVECO Group
- MBDA - Leonardo
- Solvay Specialty Polymers S.p.A.
- TOYOTA Motor Europe - Bruxelles, BE
- Toyota Tech. Institute - Japan
Projects and publications
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Selected funded research projects
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HIGH PERFORMING ELECTRICALLY RECHARGEABLE ZINC-AIR BATTERIES FOR SUSTAINABLE MID-TERM ENERGY STORAGE
GERBALDI CLAUDIO
2023 - 2027 (Current) -
HIGH VOLTAGE, ROOM TEMPERATURE SINGLE-ION POLYMER ELECTROLYTE FOR SAFER ALL SOLID STATE LITHIUM METAL BATTERIES
GERBALDI CLAUDIO
2022 - 2026 (Current) -
ENABLING HIGH-ENERGY, ROOM TEMPERATURE ALL SOLID-STATE LITHIUM METAL BATTERIES WITH ADVANCED POLYMER-BASED ELECTROLYTES AND HIGH-VOLTAGE CATHODES THROUGH ENHANCED INTERFACE CONTROL
GERBALDI CLAUDIO
2023 - 2025 (Current) -
BATTERIES EUROPE SECRETARIAT - BEST
GERBALDI CLAUDIO
2022 - 2025 (Current) -
DEMONSTRATION OF A HIGH-CAPACITY ANODE-LESS SOLID STATE LITHIUM BATTERY
GERBALDI CLAUDIO
2023 - 2024 (Current) -
MULTISENSOR SORTING TOOLS IN A CIRCULAR ECONOMY APPROACH FOR THE EFFICIENT RECYCLING OF PVB INTERLAYER MATERIAL IN HIGH-QUALITY PRODUCTS FROM LAMINATED GLASS CONSTRUCTION AND DEMOLITION WASTES
GERBALDI CLAUDIO
2021 - 2024 (Current) -
INDIVIDUAZIONE DI UN PROCESSO INDUSTRIALE SCALABILE PER LA PRODUZIONE DI UNA GIC TERMICAMENTE ESPANDIBILE
GERBALDI CLAUDIO
2022 - 2023 (Completed) -
SILICON ALLOYING ANODES FOR HIGH ENERGY DENSITY BATTERIES COMPRISING LITHIUM RICH CATHODES AND SAFE IONIC LIQUID BASED ELECTROLYTES FOR ENHANCED HIGH VOLTAGE PERFORMANCE.
GERBALDI CLAUDIO, SMEACETTO FEDERICO
2019 - 2023 (Completed) -
POLYSTORAGE - EUROPEAN TRAINING NETWORK IN INNOVATIVE POLYMERS FOR NEXT-GENERATION ELECTROCHEMICAL ENERGY STORAGE
GERBALDI CLAUDIO
2019 - 2023 (Completed) -
TOWARDS SUSTAINABLE, HIGH-PERFORMING, ALL-SOLID-STATE SODIUM-ION BATTERIES
GERBALDI CLAUDIO
2019 - 2022 (Completed) -
EUROPEAN INFRASTRUCTURE POWERING THE INTERNET OF THINGS
CERQUITELLI TANIA, GERBALDI CLAUDIO
2018 - 2021 (Completed)
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HIGH PERFORMING ELECTRICALLY RECHARGEABLE ZINC-AIR BATTERIES FOR SUSTAINABLE MID-TERM ENERGY STORAGE
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Selected recent publications
2023
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Agarose-based Gel Electrolytes for Sustainable Primary and Secondary Zinc-Air Batteries
Article
García-Gaitán, Estibaliz; Carmen Morant-Miñana, María; Frattini, Domenico; Maddalena, Lorenza; Fina, Alberto; Gerbaldi, Claudio; Cantero, Igor; Ortiz-Vitoriano, Nagore
CHEMICAL ENGINEERING JOURNAL
Elsevier
Vol.472 pp.17 (pp.1-17) ISSN:1385-8947 DOI:10.1016/j.cej.2023.144870 -
A Direct Real-Time Observation of Anion Intercalation in Graphite Process and Its Fully Reversibility by SAXS/WAXS Techniques
Article
Greco, G.; Elia, G. A.; Hermida-Merino, D.; Hahn, R.; Raoux, S.
SMALL METHODS
Wiley
pp.8 ISSN:2366-9608 DOI:10.1002/smtd.202201633 -
Revealing the competitive effect of N2 and H2O towards CO2 adsorption in N-rich ordered mesoporous carbons
Article
Maruccia, E.; Piovano, A.; Lourenço, M. A. O.; Priamushko, T.; Cavallo, M.; Bocchini, S.; Bonino, F.; Pirri, F.; Kleitz, F.; Gerbaldi, C.
MATERIALS TODAY SUSTAINABILITY
Elsevier
Vol.21 pp.14 ISSN:2589-2347 DOI:10.1016/j.mtsust.2022.100270
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Li1.4Al0.4Ge0.4Ti1.4(PO4)3 promising NASICON-structured glass-ceramic electrolyte for all-solid-state Li-based batteries: Unravelling the effect of diboron trioxide
Article
Saffirio, S.; Falco, M.; Appetecchi, G. B.; Smeacetto, F.; Gerbaldi, C.
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Elsevier Ltd
Vol.42 pp.10 (pp.1023-1032) ISSN:0955-2219 DOI:10.1016/j.jeurceramsoc.2021.11.014
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Solid-State Post Li Metal Ion Batteries: A Sustainable Forthcoming Reality?
Article
Ferrari, S.; Falco, M.; Munoz-Garcia, A. B.; Bonomo, M.; Brutti, S.; Pavone, M.; Gerbaldi, C.
ADVANCED ENERGY MATERIALS
John Wiley and Sons Inc
Vol.11 pp.30 ISSN:1614-6832 DOI:10.1002/aenm.202100785 -
Unique Carbonate-Based Single Ion Conducting Block Copolymers Enabling High-Voltage, All-Solid-State Lithium Metal Batteries
Article
Lingua, G.; Grysan, P.; Vlasov, P. S.; Verge, P.; Shaplov, A. S.; Gerbaldi, C.
MACROMOLECULES
American Chemical Society
Vol.54 pp.14 (pp.6911-6924) ISSN:0024-9297 DOI:10.1021/acs.macromol.1c00981
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Simultaneous X-Ray Diffraction and Tomography Operando Investigation of Aluminum/Graphite Batteries
Article
Elia, G. A.; Greco, G.; Kamm, P. H.; Garcia-Moreno, F.; Raoux, S.; Hahn, R.
ADVANCED FUNCTIONAL MATERIALS
Wiley-VCH Verlag
Vol.30 pp.9 ISSN:1616-301X DOI:10.1002/adfm.202003913 -
Recent advances in eco-friendly and cost-effective materials towards sustainable dye-sensitized solar cells
Article
Mariotti, N.; Bonomo, M.; Fagiolari, L.; Barbero, N.; Gerbaldi, C.; Bella, F.; Barolo, C.
GREEN CHEMISTRY
Royal Society of Chemistry
Vol.22 pp.51 (pp.7168-7218) ISSN:1463-9262 DOI:10.1039/D0GC01148G
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UV-crosslinked composite polymer electrolyte for high-rate, ambient temperature Li-based batteries
Proceeding
Falco, M.; Castro, L.; Bella, F.; Meligrana, G.; Smeacetto, F.; Cerri, Isotta Maria; Gerbaldi, C.
In: Titolo volume non avvalorato
Società Chimica Italiana (ITALIA)
Giornate dell’Elettrochimica Italiana (GEI 2019) (Padua (Italy)) 8-12 September 2019
pp.1 -
Understanding the Effect of UV-Induced Cross-Linking on the Physicochemical Properties of Highly Performing PEO/LiTFSI-Based Polymer Electrolytes
Article
Falco, M.; Simari, C.; Ferrara, C.; Nair, J. R.; Meligrana, G.; Bella, F.; Nicotera, I.; Mustarelli, P.; Winter, M.; Gerbaldi, C.
LANGMUIR
American Chemical Society
Vol.35 pp.10 (pp.8210-8219) ISSN:1520-5827 DOI:10.1021/acs.langmuir.9b00041
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Spray‐Dried Mesoporous Mixed Cu‐Ni Oxide@Graphene Nanocomposite Microspheres for High Power and Durable Li‐Ion Battery Anodes
Article
Lefrançois Perreault, L.; Colò, F.; Meligrana, G.; Kim, K.; Fiorilli, S.; Bella, F.; Nair, J. R.; Vitale-Brovarone, C.; Florek, J.; Kleitz, F.; Gerbaldi, C.
ADVANCED ENERGY MATERIALS
John Wiley & Sons, Inc.
Vol.8 pp.12 (pp.1802438-1-1802438-12) ISSN:1614-6840 DOI:10.1002/aenm.201802438
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Light-cured polymer electrolytes for safe, low-cost and sustainable sodium-ion batteries
Article
Colo', Francesca; Bella, Federico; Nair, JIJEESH RAVI; Gerbaldi, Claudio
JOURNAL OF POWER SOURCES
Elsevier B.V.
Vol.365 pp.10 (pp.293-302) ISSN:0378-7753 DOI:10.1016/j.jpowsour.2017.08.079 -
Single-ion block copolymer electrolytes based on poly(ethylene oxide) and methacrylic sulphonamide for lithium batteries
Proceeding
Porcarelli, Luca; Shaplov, A. S.; Aboudzadeh, M. A.; Bella, Federico; Nair, JIJEESH RAVI; Gerbaldi, Claudio; Mecerreyes, D.
In: Titolo volume non avvalorato
European Polymer Federation (FRANCIA)
16th EPF European Polymer Congress (Lyon (France)) July 2-7, 2017
pp.1
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Exceptional long-life performance of lithium-ion batteries using ionic liquid-based electrolytes
Article
Elia, G. A.; Ulissi, U.; Jeong, S.; Passerini, S.; Hassoun, J.
ENERGY & ENVIRONMENTAL SCIENCE
Royal Society of Chemistry
Vol.9 pp.11 (pp.3210-3220) ISSN:1754-5692 DOI:10.1039/c6ee01295g -
Improving efficiency and stability of perovskite solar cells with photocurable fluoropolymers
Article
Bella, Federico; Griffini, G.; Correa Baena, J. P.; Saracco, Guido; Grätzel, M.; Hagfeldt, A.; Turri, S.; Gerbaldi, Claudio
SCIENCE
American Association for the Advancement of Science
Vol.354 pp.4 (pp.203-206) ISSN:1095-9203 DOI:10.1126/science.aah4046 -
Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries
Article
Porcarelli, Luca; Gerbaldi, Claudio; Bella, Federico; Nair, JIJEESH RAVI
SCIENTIFIC REPORTS
Macmillan Publishers
Vol.6 pp.14 (pp.19892-1-19892-14) ISSN:2045-2322 DOI:10.1038/srep19892
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Innovative high performing metal organic framework (MOF)-laden nanocomposite polymer electrolytes for all-solid-state lithium batteries
Article
Gerbaldi, Claudio; Nair, JIJEESH RAVI; Anbu Kulandainathan, M.; Senthil Kumar, R.; Ferrara, C.; Mustarelli, P.; Stephan, A. M.
JOURNAL OF MATERIALS CHEMISTRY. A
ROYAL SOC CHEMISTRY
Vol.2 pp.7 (pp.9948-9954) ISSN:2050-7488 DOI:10.1039/c4ta01856g -
Multi-functional energy conversion and storage electrodes using flower-like Zinc oxide nanostructures
Article
Cauda, Valentina Alice; Pugliese, Diego; Garino, Nadia; Sacco, Adriano; Bianco, Stefano; Bella, Federico; Lamberti, Andrea; Gerbaldi, Claudio
ENERGY
Elsevier
Vol.65 pp.8 (pp.639-646) ISSN:0360-5442 DOI:10.1016/j.energy.2013.12.025
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Microfibrillated cellulose as reinforcement for Li-ion battery polymer electrolytes with excellent mechanical stability
Article
Chiappone, Annalisa; Nair, JIJEESH RAVI; Gerbaldi, Claudio; Jabbour, Lara; Bongiovanni, Roberta Maria; Zeno, E.; Beneventi, D.; Penazzi, Nerino
JOURNAL OF POWER SOURCES
Elsevier
Vol.196 pp.9 (pp.10280-10288) ISSN:0378-7753 DOI:10.1016/j.jpowsour.2011.07.015
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Hydrothermal synthesis of high surface LiFePO4 powders as cathode for Li-ion cells
Article
Meligrana, Giuseppina; Gerbaldi, Claudio; A., Tuel; Bodoardo, Silvia; Penazzi, Nerino
JOURNAL OF POWER SOURCES
elsevier
Vol.160 pp.7 (pp.516-522) ISSN:0378-7753 DOI:10.1016/j.jpowsour.2005.12.067
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Agarose-based Gel Electrolytes for Sustainable Primary and Secondary Zinc-Air Batteries