ALL-Polymer
Specific mission
The research activities of the ALL-polymer-group are focused on different aspects of polymer engineering, including the design and formulation of new compounds based on thermoplastic matrices (also biopolymers or recycled polymers) suitable for specific applications, the investigation of structure-property-processing relationships in polymers, polymer blends and polymer composite systems and the overall rheological, physico-chemical, thermal, mechanical and fire characterization of polymer-based systems (bulk materials, thin films, foams, and fabrics).
Main research Topics
ALL-POLYMER GROUP is developing the following research topics:
- Polymer processing: research activities in this topic include the evaluation of the effects of different processing techniques on the final properties of the formulated materials, the optimization of the processing conditions (also with the utilization of simulation software for injection molding and compounding), the setup of processing-rheology relationships, the design of polymer-based materials suitable for specific processing operations (such as film blowing or 3D-printing).
- Development of polymer-based systems and investigation on the structure-property relationships: this research activity concerns the design, preparation, and characterization of polymer blends and composite materials containing micro- or nano-fillers (such as talc, silica, calcium carbonate, nanoclays, graphene and graphene-like materials).
- Surface and bulk flame retardant treatments performed on different polymeric substrates (films, foams and fabrics): different additives and flame retardants, also including bio-sourced products are designed, applied, and assessed. (Nano)particle absorption, sol-gel methods and layer by layer depositions are exploited and the fire performance is thoroughly evaluated by means of flammability (UL94 and LOI) and forced combustion (cone calorimetry) tests.
- Design, preparation and characterization of UV- and UV-LED curable coatings: multifunctional coatings showing enhanced thermo-mechanical, flame retardant, electrical and barrier properties are investigated. This research topic also includes the formulation of recipes suitable for Stereolithography and the overall characterization of their performances.
- Development of sustainable polymer-based materials: studies in this topic concern the design, preparation, and characterization of polymer systems based on bio-derived and/or bio-degradable polymers (also suitable for applications at industrial level), formulation of biopolymer-based blends, design of composite systems containing fillers derived from industrial and agro-industrial wastes, utilization of polymers recovered from recycling processes and up-cycling strategies.
Main partnerships
- Universitat Rovira i Virgili, Tarragona, Spain;
- National Engineering Research Center of Flame Retardant Materials, School of Materials, Beijing Institute of Technology P.R.China;
- Centre Català del Plàstic (CCP) - Unversitat Politècnica de Catalunya BarcelonaTech (EEBE-UPC);
- Università di Genova;
- Università di Sassari;
- Università di Bergamo;
- Università di Parma;
- Università di Bologna;
- CNR-IPCB Portici;
- CNR-ISMAC Milano;
- CNR-STEMS Torino;
- ENEA Centro ricerche Casaccia
- Consorzio Proplast
- Michelin Italia
Projects and publications
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Selected recent publications
2025-
Mechanical recycling of HDPE-based packaging: Interplay between cross contamination, aging and reprocessing
Article
Gnoffo, Chiara; Arrigo, Rossella; Frache, Alberto
POLYMER DEGRADATION AND STABILITY
Elsevier
Vol.236 pp.8 ISSN:0141-3910 DOI:10.1016/j.polymdegradstab.2025.111290 -
High Melt Strength Recycled High-Density Polyethylene: Evaluation of a Novel Route for Targeting the Polymer Microstructure
Article
Bernagozzi, Giulia; Arrigo, Rossella; Frache, Alberto
POLYMERS
MDPI
Vol.17 pp.14 ISSN:2073-4360 DOI:10.3390/polym17030382 -
Advanced flame-retardant biocomposites: Polylactic acid reinforced with green gallic acid‑iron‑phosphorus coated flax fibers
Article
Pantaleoni, Alessia; Marrocchi, Assunta; Russo, Pietro; Malucelli, Giulio; Altamura, Davide; Nardelli, Francesca; Pizzanelli, Silvia; Freni, Angelo; Giannini, Cinzia; Laura Santarelli, Maria; Bavasso, Irene; Paola Bracciale, Maria; Sarasini, Fabrizio
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
Elsevier
Vol.300 pp.14 ISSN:0141-8130 DOI:10.1016/j.ijbiomac.2025.140215 -
Prediction and validation of fire parameters for a self‑extinguishing and smoke suppressant electrospun PVP‑based multilayer material through machine learning models
Article
Bifulco, Aurelio; Climaco, Immacolata; Casciello, Angelo; Passaro, Jessica; Battegazzore, Daniele; Nebbioso, Viviana; Russo, Pietro; Imparato, Claudio; Aronne, Antonio; Malucelli, Giulio
JOURNAL OF MATERIALS SCIENCE
Springer
Vol.60 pp.22 (pp.1019-1040) ISSN:1573-4803 DOI:10.1007/s10853-024-10529-3
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Plastic waste recycling in additive manufacturing: Recovery of polypropylene from WEEE for the production of 3D printing filaments
Article
Spirio, Andrea; Arrigo, Rossella; Frache, Alberto; Tuccinardi, Letizia; Tuffi, Riccardo
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
Elsevier
Vol.12 pp.11 (pp.1-11) ISSN:2213-3437 DOI:10.1016/j.jece.2024.112474 -
Towards effective recycling routes for polypropylene: influence of a repair additive on flow characteristics and processability
Article
Bernagozzi, Giulia; Arrigo, Rossella; Ponzielli, Giuseppe; Frache, Alberto
POLYMER DEGRADATION AND STABILITY
Elsevier
Vol.223 pp.9 ISSN:0141-3910 DOI:10.1016/j.polymdegradstab.2024.110714 -
Elongational flow‐induced microstructure evolutions in polypropylene/layered double hydroxides nanocomposites
Article
Gnoffo, Chiara; Arrigo, Rossella; Sisani, Michele; Frache, Alberto
POLYMER COMPOSITES
Wiley
pp.12 (pp.1-12) ISSN:0272-8397 DOI:10.1002/pc.28221 -
Multifunctional fire-resistant and flame-triggered shape memory epoxy nanocomposites containing carbon dots
Article
Bifulco, Aurelio; Imparato, Claudio; Climaco, Immacolata; Battegazzore, Daniele; Perrella, Michele; Vitiello, Giuseppe; Aronne, Antonio; Malucelli, Giulio
CHEMICAL ENGINEERING JOURNAL
Elsevier
Vol.484 pp.17 ISSN:1385-8947 DOI:10.1016/j.cej.2024.149327 -
Recycling of polyurethanes: where we are and where we are going
Article
Rossignolo, Gabriele; Malucelli, Giulio; Lorenzetti, Alessandra
GREEN CHEMISTRY
Royal Society of Chemistry
Vol.26 pp.21 (pp.1132-1152) ISSN:1463-9262 DOI:10.1039/D3GC02091F -
Evolution of the Microstructure of PP-LDHs Nanocomposites during Melt Compounding: A Simulation Approach
Article
Bernagozzi, Giulia; Arrigo, Rossella; Frache, Alberto
POLYMERS
MDPI
Vol.16 pp.15 ISSN:2073-4360 DOI:10.3390/polym16010070
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Polymer Hydrogels and Frontal Polymerization: A Winning Coupling
Article
Mariani, Alberto; Malucelli, Giulio
POLYMERS
MDPI
Vol.15 pp.33 ISSN:2073-4360 DOI:10.3390/polym15214242 -
Insights into the effect of different macromolecular architectures on the charring ability of polyethylene
Article
Frache, A.; Arrigo, R.; Malucelli, G.; Camino, G.
POLYMER DEGRADATION AND STABILITY
Elsevier
Vol.216 pp.12 ISSN:0141-3910 DOI:10.1016/j.polymdegradstab.2023.110476 -
Optimizing the Rheological and Thermal Behavior of Polypropylene-Based Composites for Material Extrusion Additive Manufacturing Processes
Article
Bernagozzi, Giulia; Battegazzore, Daniele; Arrigo, Rossella; Frache, Alberto
POLYMERS
MDPI
Vol.15 pp.15 ISSN:2073-4360 DOI:10.3390/polym15102263 -
In Situ P-Modified Hybrid Silica–Epoxy Nanocomposites via a Green Hydrolytic Sol–Gel Route for Flame-Retardant Applications
Article
Bifulco, Aurelio; Avolio, Roberto; Lehner, Sandro; Emanuela Errico, Maria; Clayden, Nigel J.; Pauer, Robin; Gaan, Sabyasachi; Malucelli, Giulio; Aronne, Antonio; Imparato, Claudio
ACS APPLIED NANO MATERIALS
ACS
Vol.6 pp.14 (pp.7422-7435) ISSN:2574-0970 DOI:10.1021/acsanm.3c00590 -
Frontal Polymerizations: From Chemical Perspectives to Macroscopic Properties and Applications
Article
Suslick, Benjamin A.; Hemmer, Julie; Groce, Brecklyn R.; Stawiasz, Katherine J.; Geubelle, Philippe H.; Malucelli, Giulio; Mariani, Alberto; Moore, Jeffrey S.; Pojman, John A.; Sottos, Nancy R.
CHEMICAL REVIEWS
ACS
Vol.123 pp.62 (pp.3237-3298) ISSN:0009-2665 DOI:10.1021/acs.chemrev.2c00686 -
Fully bio-based ternary polymer blends: structural characterization and mechanical behavior
Article
Arrigo, R.; D'Anna, A.; Frache, A.
MATERIALS TODAY SUSTAINABILITY
Elsevier
Vol.21 pp.11 ISSN:2589-2347 DOI:10.1016/j.mtsust.2022.100314
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Mechanical, electrical, thermal and tribological behavior of epoxy resin composites reinforced with waste hemp-derived carbon fibers
Article
Bartoli, Mattia; Duraccio, Donatella; Faga, Maria Giulia; Piatti, Erik; Torsello, Daniele; Ghigo, Gianluca; Malucelli, Giulio
JOURNAL OF MATERIALS SCIENCE
Springer
pp.16 ISSN:0022-2461 DOI:10.1007/s10853-022-07550-9 -
Preparation and characterization of 3D-Printed biobased composites containing micro- or nanocrystalline cellulose
Article
Palucci Rosa, Raphael; Rosace, Giuseppe; Arrigo, Rossella; Malucelli, Giulio
POLYMERS
MDPI
Vol.14 pp.21 ISSN:2073-4360 DOI:10.3390/polym14091886 -
FDM Printability of PLA Based-Materials: The Key Role of the Rheological Behavior
Article
Arrigo, Rossella; Frache, Alberto
POLYMERS
MDPI
Vol.14 pp.15 ISSN:2073-4360 DOI:10.3390/polym14091754 -
Flame retardant potential of Tetra Pak®-derived biochar for ethylene-vinyl-acetate copolymers
Article
Matta, Samuele; Bartoli, Mattia; Arrigo, Rossella; Frache, Alberto; Malucelli, Giulio
COMPOSITES. PART C, OPEN ACCESS
Elsevier
Vol.8 pp.14 ISSN:2666-6820 DOI:10.1016/j.jcomc.2022.100252 -
Rheology, Morphology and Thermal Properties of a PLA/PHB/Clay Blend Nanocomposite: The Influence of Process Parameters
Article
D'Anna, A.; Arrigo, R.; Frache, A.
JOURNAL OF POLYMERS AND THE ENVIRONMENT
Springer
Vol.30 pp.12 (pp.102-113) ISSN:1566-2543 DOI:10.1007/s10924-021-02186-3
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Thermal, dynamic-mechanical and electrical properties of UV-LED curable coatings containing porcupine-like carbon structures
Article
Arrigo, Rossella; Bartoli, Mattia; Torsello, Daniele; Ghigo, Gianluca; Malucelli, Giulio
MATERIALS TODAY COMMUNICATIONS
Elsevier
Vol.28 pp.9 ISSN:2352-4928 DOI:10.1016/j.mtcomm.2021.102630 -
Designing 3D printable polypropylene: Material and process optimisation through rheology
Article
Bertolino, M.; Battegazzore, D.; Arrigo, R.; Frache, A.
ADDITIVE MANUFACTURING
Elsevier B.V.
Vol.40 pp.9 ISSN:2214-8604 DOI:10.1016/j.addma.2021.101944 -
Dielectric spectroscopy of PP/MWCNT nanocomposites: Relationship with crystalline structure and injection molding condition
Article
Monti, M.; Zaccone, M.; Frache, A.; Torre, L.; Armentano, I.
NANOMATERIALS
MDPI AG
Vol.11 pp.14 (pp.1-14) ISSN:2079-4991 DOI:10.3390/nano11020550 -
Structure–property relationships in bionanocomposites for pipe extrusion applications
Article
Botta, Luigi; Paolo La Mantia, Francesco; Chiara Mistretta, Maria; Oliveri, Antonino; Arrigo, Rossella; Malucelli, Giulio
POLYMERS
MDPI
Vol.13 pp.13 ISSN:2073-4360 DOI:10.3390/polym13050782 -
Synthesis and characterization of UV-curable nanocellulose/ZnO/AlN acrylic flexible films: thermal, dynamic mechanical and piezoelectric response
Article
Assunta Signore, Maria; De Pascali, Chiara; Duraccio, Donatella; Malucelli, Giulio; Fioravanti, Ambra; Melissano, Enrico; Concetta Martucci, Maria; Masieri, Maurizio; Siciliano, Pietro; Francioso, Luca
JOURNAL OF APPLIED POLYMER SCIENCE
Wiley
Vol.138 pp.15 ISSN:0021-8995 DOI:10.1002/app.49731
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Mechanical recycling of HDPE-based packaging: Interplay between cross contamination, aging and reprocessing
Reference laboratories
- Chemical preparation laboratory
- Functional Coatings Laboratory
- Laboratory Fire Testing
- Laboratory Plastic Processing
- Laboratory Surface Treatments
- Polymeric Characterization Laboratory